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Syntheses and kinetic studies of cyclisation-based self-immolative spacers

1 Jan 2017Organic & Biomolecular Chemistry

DOI : 10.1039/c7ob00121e

Authors

Steve Huvelle, Ahmed Alouane, Thomas Le Saux, Ludovic Jullien, Frédéric Schmidt

Abstract

Photochemical activation has allowed the precise determination of the disassembly times of cyclisation-based self-immolative spacers. Results confirmed large differences with previously studied elimination-based self-immolative spacers.